An Energy-Saving Solution for Hydrogen Conductivity Measurement Systems in Thermal Power Plant Boiler Water Based on Deep Regeneration Technology Using Ion-Exchange Resins
Main Article Content
Abstract
To address discontinuous boiler water hydrogen conductivity measurement, low resin exchange output, high plant energy consumption, and frequent offline regeneration of resin columns in thermal power plants, an accuracy-constrained energy consumption optimization model for deep regeneration of ion exchange resins was developed. Based on the traditional hydrogen-type cation exchange resin column measurement process, the model integrates hydrogen generation through ionization, ion migration, online resin reset, and four-channel independent regeneration control, forming a closed-loop framework of “capacity identification—trend determination—liquid volume and time optimization— accuracy-constrained control.” Real-time parameters, including flow rate, pressure, temperature, hydrogen conductivity, regeneration voltage, and current, are collected to identify resin exchange-capacity decay, determine regeneration timing and triggering conditions, and optimize regeneration power and cycle duration. The optimization is constrained by a measurement error of ≤3% and a cation removal efficiency of ≥99.9%. A 30-day test on Huayuan Unit 1 and Unit 3 at 20 test points showed that the average effective resin exchange quantity increased from 0.97 mmol·mL−1 to 1.50 mmol·mL−1, the average failure interval extended from 7.7 days to 29.3 days, and total system energy consumption decreased from 173.4 kWh to 112.5 kWh, representing a 35.12% reduction. After deep regeneration, the average relative error decreased to 1.14%, and the effective data rate increased to 99.36%. These results indicate that the model reduces regeneration and maintenance energy consumption while ensuring the accuracy of boiler water hydrogen conductivity measurement.
Downloads
Article Details

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).
References
J. Godifredo, L. Ruiz, S. Hernández, et al., “Recovering nitrogen from anaerobic membrane bioreactor permeate using a natural zeolite ion exchange column,” Water, vol. 16, no. 19, p. 2820, 2024, doi: 10.3390/w161 92820.
S. Y. Yeoh, K. W. Lai, S. Y. Pung, et al., “Optimising brine regeneration of ion-exchange resins: Effects of pre-treatment temperature, brine concentration, and ratio,” Clean Technologies and Environmental Policy, vol. 28, no. 3, p. 62, 2026, doi: 10.1007/s10098-025-03367-7.
N. M. Marin, M. Nita Lazar, M. Popa, et al., “Current trends in development and use of polymeric ion-exchange resins in wastewater treatment,” Materials, vol. 17, no. 23, p. 5994, 2024, doi: 10.3390/ma17235994.
J. Wullenweber, J. Bennert, T. Mantel, et al., “Characterizing macroporous ion exchange membrane adsorbers for natural organic matter (NOM) removal—adsorption and regeneration behavior,” Membranes, vol. 14, no. 6, p. 124, 2024, doi: 10.3390/membranes14060124.
M. Bernardi, A. L. Hantson, G. Caulier, et al., “Ni2+ removal by ion exchange resins and activated carbon: A benchtop NMR study,” International Journal of Environmental Science and Technology, vol. 21, no. 13, pp. 8337–8360, 2024, doi: 10.1007/s13762-024-05547-2.
A. Mohammed, C. Mohammed, A. Mautner, et al., “On the performance of Sargassum-derived calcium alginate ion exchange resins for Pb2+ adsorption: Batch and packed bed applications,” Environmental Science and Pollution Research, vol. 31, no. 21, pp. 31224–31239, 2024, doi: 10.1007/s11356-024-33314-w.
E. Apraku, C. M. Laguna, R. M. Wood, et al., “Enhancing resource recovery through electro-assisted regeneration of an ammonia-selective cation exchange resin,” ACS ES&T Water, vol. 4, no. 10, pp. 4521–4532, 2024, doi: 10.1021/acsestwater.4c00543.
Y. Rasouli, B. Barbeau, R. Maltais-Tariant, et al., “Impact of cleaning on membrane performance during surface water treatment: A hybrid process with biological ion exchange and gravity-driven membranes,” Membranes, vol. 14, no. 2, p. 33, 2024, doi: 10.3390/membranes14020033.
C. Graham, C. Kassar, and T. H. Boyer, “Alcohol regeneration of anion exchange resin loaded with per- and polyfluoroalkyl substances and organic contaminants,” AWWA Water Science, vol. 6, no. 4, p. e1380, 2024, doi: 10.1002/aws2.1380.
K. Zimmermann, P. Sampara, R. Ziels, et al., “Biological contributions to biological ion exchange,” Environmental Science: Water Research & Technology, vol. 10, no. 4, pp. 877–888, 2024, doi: 10.1039/d3ew00766a.
M. F. Ahmer and M. K. Uddin, “Structure properties and industrial applications of anion exchange resins for the removal of electroactive nitrate ions from contaminated water,” RSC Advances, vol. 14, no. 45, pp. 33629–33648, 2024, doi: 10.1039/d4ra03871a.
H. Asim, H. Zeidan, and M. E. Marti, “Effective isolation of succinic acid from aqueous media with the use of anion exchange resins,” RSC Advances, vol. 14, no. 24, pp. 16765–16777, 2024, doi: 10.1039/d4ra02110j.
A. El-Tantawy, E. M. Abu Elgoud, and S. E. A. Sharaf El-Deen, “Evaluation of anion exchange resin for sorption of selenium (IV) from aqueous solutions,” BMC Chemistry, vol. 19, no. 1, p. 10, 2025, doi: 10.1186/s130 65-024-01356-3.
A. L. Mungan, E. A. Hjelvik, A. P. Straub, et al., “A hybrid anion exchanger with nanoscale zero valent iron for trace hexavalent chromium removal from drinking water,” Environmental Science: Advances, vol. 3, no. 11, pp. 1598–1615, 2024, doi: 10.1039/d4va00246f.
K. Chruszcz-Lipska and E. Szostak, “A study of the structure of an anion exchange resin with a quaternary ammonium functional group by using infrared spectroscopy and DFT calculations,” Materials, vol. 17, no. 24, p. 6132, 2024, doi: 10.3390/ma17246132.
S. Bergamasco, L. A. Hein, L. Silvestri, et al., “Innovative Nafion- and lignin-based cation exchange materials against standard resins for the removal of heavy metals during water treatment,” Separations, vol. 11, no. 12, p. 357, 2024, doi: 10.3390/separations11120357.
F. Galluccio, A. Santi, E. Rizzi, et al., “An integrated strategy for predisposal of spent cation-exchange resins by repurposing industrial by-products,” Sustainability, vol. 17, no. 18, p. 8241, 2025, doi: 10.3390/su17188241.
V. Romanovski and V. Gruzinova, “Aggregate from spent ion-exchange resins for petroleum products removal from wastewater,” Waste and Biomass Valorization, vol. 17, no. 2, pp. 857–865, 2026, doi: 10.1007/s12649-025-03158-7.
A. L. Ling, T. Stegner, M. Thompson, et al., “Spent media management pathways for PFAS treatment applications,” Water Environment Research, vol. 97, no. 7, p. e70130, 2025, doi: 10.1002/wer.70130.
W. H. DiGuiseppi, C. J. Newell, G. Carey, et al., “Available and emerging liquid treatment technologies for PFASs,” Remediation Journal, vol. 34, no. 3, p. e21782, 2024, doi: 10.1002/rem.21782.
A. Q. Jasim and S. K. Ajjam, “Removal of heavy metal ions from wastewater using ion exchange resin in a batch process with kinetic isotherm,” South African Journal of Chemical Engineering, vol. 49, no. 1, pp. 43–54, 2024, doi: 10.1016/j.sajce.2024.04.002.